9-Iodophenalenone and 9-trifluoromethanesulfonyloxyphenalenone: convenient entry points to new phenalenones functionalised at the 9-position. Iodine-carbonyl interaction studies by X-ray crystallography
Author:
Affiliation:
1. WestCHEM
2. School of Chemistry
3. University of Glasgow
4. Glasgow G12 8QQ, UK
Abstract
Triflic anhydride acts like a key to the unreactive, “locked” 9-hydroxyphenalenone, providing access to new phenalenones functionalised in 9-position as well as to a phenalenyl-annelated isoxazole.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/RA/C4RA00178H
Reference33 articles.
1. 1H-Phenalen-1-one: Photophysical Properties and Singlet-Oxygen Production
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3. Phototoxic Phytoalexins. Processes that Compete with the Photosensitized Production of Singlet Oxygen by 9-Phenylphenalenones†
4. Light- and singlet oxygen-mediated antifungal activity of phenylphenalenone phytoalexins
5. Light and Singlet Oxygen in Plant Defense Against Pathogens: Phototoxic Phenalenone Phytoalexins
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