Cu@CuCl-visible light co-catalysed chlorination of C(sp3)–H bonds with MCln solution and photocatalytic serial reactor-based synthesis of benzyl chloride-Reference-Cited by-同舟云学术

Cu@CuCl-visible light co-catalysed chlorination of C(sp3)–H bonds with MCln solution and photocatalytic serial reactor-based synthesis of benzyl chloride

Published:2022 Issue:1 Volume:24 Page:384-393
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Zhang Qi¹²,Liu Shouxin²^ORCID,Tian Xia²,Liu Yidong²,Fan Shiming²,Huang Baibiao¹,Whiting Andrew³^ORCID

Affiliation:

1. State Key Lab of Crystal Materials, Shandong University, Jinan 250100, People's Republic of China

2. State Key Laboratory of Molecular Chemistry for Drug, Hebei University of Science & Technology, Shijiazhuang 050018, People's Republic of China

3. Centre for Sustainable Chemical Processes, Department of Chemistry, Science Laboratories, Durham University, South Road, Durham, DH1 3LE, UK

Abstract

A highly selective and sustainable chlorination of aliphatic C–Hs with inorganic chloride MCln as a chlorine source in a weak acidic water solution without strong oxidising agents under the co-catalysis of visible light is reported.

Funder

National Natural Science Foundation of China

National Key Research and Development Program of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/GC/D1GC03092B

Reference53 articles.

1. Halogen-Mediated Conversion of Hydrocarbons to Commodities

2. A Base-Resistant Metalloporphyrin Metal–Organic Framework for C–H Bond Halogenation