A copper(ii)-coordination polymer based on a sulfonic–carboxylic ligand exhibits high water-facilitated proton conductivity-Reference-Cited by-同舟云学术

A copper(ii)-coordination polymer based on a sulfonic–carboxylic ligand exhibits high water-facilitated proton conductivity

Published:2019 Issue:29 Volume:48 Page:11034-11044
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Tayade Sakharam B.¹²³⁴^ORCID,lllathvalappil Rajith⁵⁶⁷⁴⁸,Lapalikar Vaidehi¹²³⁴,Markad Datta⁹¹⁰¹¹⁴,Kurungot Sreekumar⁵⁶⁷⁴⁸^ORCID,Pujari Bhalchandra¹²²³⁴^ORCID,Kumbhar Avinash S.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Savitribai Phule Pune University

3. Pune 411007

4. India

5. Physical and Materials Chemistry Division

6. National Chemical Laboratory

7. Pune 411008

8. Academy of Scientific and Innovative Research (AcSIR)

9. Department of Chemical Sciences

10. Indian Institute of Science Education and Research Mohali

11. Mohali

12. Centre for Modelling and Simulation

Abstract

The coordination polymer {[Cu₂(sba)₂(bpg)₂(H₂O)₃]·5H₂O}_n encapsulates arrays of water molecules H-bonded to the framework displaying a high conductivity value of 0.94 × 10⁻² S cm⁻¹ with an activation energy of 0.64 eV.

Funder

Council of Scientific and Industrial Research, India

Department of Science and Technology, Ministry of Science and Technology

Savitribai Phule Pune University

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT01983A

Reference83 articles.