The origin of anode–electrolyte interfacial passivation in rechargeable Mg-metal batteries

Author:

Zhang Jinlei1,Liu Jing12,Wang Min1,Zhang Zhonghua13ORCID,Zhou Zhenfang1,Chen Xi4,Du Aobing3ORCID,Dong Shanmu3,Li Zhenjiang1ORCID,Li Guicun1ORCID,Cui Guanglei3ORCID

Affiliation:

1. College of Materials Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China

2. Department of Pharmacy, Jining Medical University, Rizhao 276826, P. R. China

3. Qingdao Industrial Energy Storage Research Institute, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, P. R. China

4. Department of Physics, Xi’an Jiaotong-Liverpool University, Suzhou 215123, P. R. China

Abstract

The formation of H2O molecules competitively solvating Mg-ion solvation structures and their decomposition in electrochemical and/or chemical reaction pathways with inherent H2O ligands result in dendritic and passivated electrodeposition.

Funder

National Natural Science Foundation of China

China Postdoctoral Science Foundation

Natural Science Foundation of Jiangsu Province

Natural Science Foundation of Shandong Province

National Science Fund for Distinguished Young Scholars

Xi’an Jiaotong-Liverpool University

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

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