Synthesis and characterisation of cycloruthenated benzhydrazone complexes: catalytic application to selective oxidative cleavage of olefins to aldehydes

Author:

Manikandan Thimma Sambamoorthy12345,Ramesh Rengan12345,Semeril David678910

Affiliation:

1. Centre for Organometallic Chemistry

2. School of Chemistry

3. Bharathidasan University

4. Tiruchirappalli – 620 024

5. India

6. Laboratoire de Chimie Inorganique et Catalyse

7. Institut de Chimie

8. Universite de Strasbourg

9. UMR 7177

10. CNRS

Abstract

The synthesis and structural characterisation of cyclometalated ruthenium(ii) aroylhydrazone complexes have been described. The complexes were developed as effective catalysts for oxidative cleavage of olefin reactions.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference48 articles.

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2. R. Stewart , Oxidation in Organic Chemistry, ed. K. B. Wiberg, Academic Press, New York, 1965

3. M. Hudlicky , Oxidations in Organic Chemistry, American Chemical Society Monograph 186, American Chemical Society, Washington, DC, 1990

4. R. C. Larock , Comprehensive Organic Transformations, Wiley-VCH, New York, 2nd edn, 1999, p. 1234

5. D. G. Lee and T.Chen, Comprehensive organic synthesis, ed. B. M. Trost and I. Fleming, Pergamon Press, Oxford, 1991, vol. 7, p. 541

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