Local magnetic spin mismatch promoting photocatalytic overall water splitting with exceptional solar-to-hydrogen efficiency

Author:

Li Yiyang1ORCID,Wang Zihan2,Wang Yiqi2,Kovács András3,Foo Christopher1ORCID,Dunin-Borkowski Rafal E.3ORCID,Lu Yunhao4,Taylor Robert A.5,Wu Chen2ORCID,Tsang Shik Chi Edman1ORCID

Affiliation:

1. Wolfson Catalysis Centre, Department of Chemistry, University of Oxford, Oxford, OX1 3QR, UK

2. School of Materials Science and Engineering, State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou, 310027, China

3. Ernst Ruska-Centre for Microscopy and Spectroscopy with Electrons and Peter Grünberg Institute, Forschungszentrum Jülich, 52425 Jülich, Germany

4. Zhejiang Province Key Laboratory of Quantum Technology and Device, Department of Physics, Zhejiang University, Hangzhou, 310027, China

5. Clarendon Laboratory, Department of Physics, University of Oxford, Oxford, OX1 3PU, UK

Abstract

A local-magnetic-field-promoted photocatalytic overall water splitting system is developed for the Fe3O4/N-TiO2 catalyst, and an unprecedented solar-to-hydrogen efficiency of 11.9 ± 0.5% is achieved at 270 °C.

Funder

Engineering and Physical Sciences Research Council

Zhejiang University

Horizon 2020

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

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