A P–H functionalized Al/P-based frustrated Lewis pair – hydrophosphination of nitriles, ring opening with cyclopropenones and evidence of PC double bond formation-Reference-Cited by-同舟云学术

A P–H functionalized Al/P-based frustrated Lewis pair – hydrophosphination of nitriles, ring opening with cyclopropenones and evidence of PC double bond formation

Published:2018 Issue:25 Volume:47 Page:8402-8417
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Keweloh Lukas¹²³,Aders Niklas¹²³,Hepp Alexander¹²³,Pleschka Damian¹²³,Würthwein Ernst-Ulrich⁴⁵⁶³^ORCID,Uhl Werner¹²³^ORCID

Affiliation:

1. Institut für Anorganische und Analytische Chemie der Universität Münster

2. D-48149 Münster

3. Germany

4. Organisch-Chemisches Institut and Center for Multiscale Theory and Computation (CMTC)

5. Westfälische Wilhelms-Universität Münster

6. 48149 Münster

Abstract

A P–H functionalized FLP reacted with RX-CN by hydrophosphination. Ring opening by treatment with cyclopropenthione resulted in PC bond formation.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT01836G

Reference102 articles.

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