Low temperature insights into the crystal and magnetic structure of a neutral radical ferromagnet

Author:

Robertson Craig M.1ORCID,Winter Stephen M.2,Howard Judith A. K.3ORCID,Probert Michael R.4ORCID,Oakley Richard T.5ORCID

Affiliation:

1. Department of Chemistry, University of Liverpool, Liverpool L69 7ZD, UK

2. Department of Physics, Wake Forest University, Winston-Salem, NC 27109, USA

3. Department of Chemistry, Durham University, Durham, DH1 3LE, UK

4. Chemistry, School of Natural and Environmental Sciences, Newcastle University, Newcastle upon Tyne, NE1 7RU, UK

5. Department of Chemistry, University of Waterloo, Waterloo, Ontario N2L 3G1, Canada

Abstract

Contraction of the unit cell of the neutral radical ferromagnet 1a at T = 2 K leads to a decrease in slippage of the radical π-stacks and an increase in axial ferromagnetic exchange interactions.

Funder

Engineering and Physical Sciences Research Council

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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