Intramolecular Hg⋯π interactions of d-character with non-bridging atoms in mercury

Intramolecular Hg⋯π interactions of d-character with non-bridging atoms in mercury–aryl complexes

Published:2016 Issue:36 Volume:45 Page:14035-14038
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Lannes A.¹²³⁴⁵,Manceau A.¹²³⁴⁵,Rovezzi M.⁶⁷⁵,Glatzel P.⁶⁷⁵,Joly Y.⁸²³⁹⁵,Gautier-Luneau I.⁸²³⁹⁵

Affiliation:

1. ISTerre

2. Université Grenoble Alpes

3. CNRS

4. 38058 Grenoble

5. France

6. European Synchrotron Radiation Facility (ESRF)

7. 38000 Grenoble

8. Institut Néel

9. 38042 Grenoble

Abstract

The late transition metal mercury, known for its propensity to not share 5d electrons, actually does so in short-range π-bonding and medium- to long-range π-interactions.

Funder

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT02200F

Reference19 articles.

1. N. N. Greenwood and A.Earnshaw, Chemistry of the Elements, Pergamon Press, Oxford, 1984

2. F. A. Cotton , G.Wilkinson, C. A.Murillo and M.Bochmann, Advanced Inorganic Chemistry, John Wiley & Sons, New York, 6th edn, 1999

3. Lewis Acidic Behavior of Fluorinated Organomercurials

4. Impact of high π-density on the coordination properties of π-excess aromatic neutral σ2P ligands – P(π)-donor bonds to Ag+and HgCl2

5. Structure, Bonding, and Stability of Mercury Complexes with Thiolate and Thioether Ligands from High-Resolution XANES Spectroscopy and First-Principles Calculations

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