Massive acceleration of S<sub>N</sub>2 reaction using the oriented external electric field-Reference-Cited by-同舟云学术

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Massive acceleration of S_N2 reaction using the oriented external electric field

Published:2024 Issue:33 Volume:15 Page:13486-13494
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Tang Chun¹,Su Meiling¹,Lu Taige¹,Zheng Jueting¹,Wang Juejun¹,Zhou Yu¹,Zou Yu-Ling¹,Liu Wenqing¹,Huang Ruiyun¹,Xu Wei¹,Chen Lijue¹,Zhang Yanxi¹,Bai Jie¹,Yang Yang¹^ORCID,Shi Jia¹,Liu Junyang¹^ORCID,Hong Wenjing¹^ORCID

Affiliation:

1. State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM), Xiamen University, Xiamen, China

Abstract

The SN2 reaction, typically enhanced by polar solvents, can be accelerated using external electric fields within nanogaps in non-polar solvents.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Fujian Provincial Department of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC03759F

Reference57 articles.

1. Enzymatic Mechanisms of Phosphate and Sulfate Transfer

2. Über die Affinitätskoeffizienten der Alkylhaloide und der Amine

3. Analysis of solvent effects on the Menshutkin reaction

4. A priori computation of a solvent-enhanced SN2 reaction profile in water: the Menshutkin reaction

5. Catalysis of Methyl Transfer Reactions by Oriented External Electric Fields: Are Gold–Thiolate Linkers Innocent?

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