Selective recognition of uranyl ions from bulk of thorium(iv) and lanthanide(iii) ions by tetraalkyl urea: a combined experimental and quantum chemical study-Reference-Cited by-同舟云学术

Selective recognition of uranyl ions from bulk of thorium(iv) and lanthanide(iii) ions by tetraalkyl urea: a combined experimental and quantum chemical study

Published:2016 Issue:25 Volume:45 Page:10319-10325
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Vats Bal Govind¹²³⁴,Das Debasish⁵²³⁴,Sadhu Biswajit⁶²³⁴,Kannan S.¹²³⁴,Pius I. C.¹²³⁴,Noronha D. M.¹²³⁴,Sundararajan Mahesh⁷²³⁴,Kumar Mukesh⁸²³⁴

Affiliation:

1. Fuel Chemistry Division

2. Bhabha Atomic Research Centre

3. Mumbai 400085

4. India

5. Fuel Reprocessing Division

6. Radiation Safety Systems Division

7. Theoretical Chemistry Section

8. Solid state physics division

Abstract

A selectivity for uranyl ions in the presence of interfering Th(iv) and other lanthanide ions from a nitric acid medium was exclusively achieved using tetraalkyl urea.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT01191H

Reference35 articles.

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4. The mechanism of the reduction of [AnO2]2+ (An = U, Np, Pu) in aqueous solution, and by Fe(ii) containing proteins and mineral surfaces, probed by DFT calculations

5. Stereognostic coordination chemistry. 1. The design and synthesis of chelators for the uranyl ion

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