A single palladium site catalyst as a bridge for converting homogeneous to heterogeneous in dimerization of terminal aryl acetylenes

Author:

Zhao Chao12345,Yu Haizhu67895,Wang Jing12345,Che Wei103115,Li Zhijun12345,Yao Tao103115ORCID,Yan Wensheng103115,Chen Min12345,Yang Jian12345,Wei Shiqiang103115ORCID,Wu Yuen12345ORCID,Li Yadong112135ORCID

Affiliation:

1. Department of Chemistry

2. iChEM (Collaborative Innovation Center of Chemistry for Energy Materials)

3. University of Science and Technology of China

4. Hefei 230026

5. China

6. Department of Chemistry and Center for Atomic Engineering of Advanced Materials

7. Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials

8. Anhui University

9. Hefei

10. National Synchrotron Radiation Laboratory

11. Hefei 230029

12. Tsinghua University

13. Beijing 100084

Abstract

Herein, we utilize the surface dangling bond of MOFs as anchoring sites to access single Pd sites embedded on a hollow MOF nanobox.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Materials Science

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