Hollow and microporous catalysts bearing Cr(iii)–F porphyrins for room temperature CO2 fixation to cyclic carbonates

Author:

Kim Myung Hyun1234,Song Taemoon15674,Seo Ue Ryung15674,Park Ji Eun15674,Cho Kyoungil1234,Lee Sang Moon894,Kim Hae Jin894,Ko Yoon-Joo1011674,Chung Young Keun15674ORCID,Son Seung Uk1234ORCID

Affiliation:

1. Department of Chemistry

2. Sungkyunkwan University

3. Suwon 16419

4. Korea

5. College of Natural Sciences

6. Seoul National University

7. Seoul 08826

8. Korea Basic Science Institute

9. Daejeon 34133

10. Laboratory of Nuclear Magnetic Resonance

11. The National Center for Inter-University Research Facilities (NCIRF)

Abstract

Hollow and microporous Cr(iii)–F porphyrin networks showed excellent catalytic activities in room temperature CO2 fixation with epoxides to cyclic carbonates due to the hollow structure and the efficient Lewis acidic activity.

Funder

National Research Foundation of Korea

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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