Nitrogen as a pnicogen?: evidence for π-hole driven novel pnicogen bonding interactions in nitromethane–ammonia aggregates using matrix isolation infrared spectroscopy and ab initio computations
Author:
Affiliation:
1. Homi Bhabha National Institute
2. Materials Chemistry & Metal Fuel Cycle Group
3. Indira Gandhi Center for Atomic Research
4. Kalpakkam – 603102
5. India
Abstract
The electrophilic role of nitrogen in hosting a pnicogen bond within model matrix isolated nitromethane–ammonia aggregates.
Funder
Department of Atomic Energy, Government of India
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2021/CP/D0CP06273A
Reference90 articles.
1. Structural Aspects of Interatomic Charge-Transfer Bonding
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3. Halogen bonding: the σ-hole
4. Boron and other Triel Lewis Acid Centers: From Hypovalency to Hypervalency
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