Faradaic processes beyond Nernst's law: density functional theory assisted modelling of partial electron delocalisation and pseudocapacitance in graphene oxides-Reference-Cited by-同舟云学术

Faradaic processes beyond Nernst's law: density functional theory assisted modelling of partial electron delocalisation and pseudocapacitance in graphene oxides

Published:2017 Issue:75 Volume:53 Page:10414-10417
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Li Junfu¹²³⁴⁵,O’Shea James⁶³⁴⁵,Hou Xianghui¹²³⁴⁵,Chen George Z.¹²³⁴⁵^ORCID

Affiliation:

1. Advanced Materials Research Group

2. Faculty of Engineering

3. University of Nottingham

4. Nottingham NG7 2RD

5. UK

6. School of Physics and Astronomy

Abstract

DFT studies of graphene oxide models suggest that the transfer of partially delocalised electrons does not follow Nernst's Law, but explain well the common experimental observations of pseudocapacitance.

Funder

China Scholarship Council

Ningbo Municipal People's Government

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CC/C7CC04344A

Reference21 articles.

1. Superior Capacitance of Functionalized Graphene

2. An Electrochemical Route to Quantitative Oxidation of Graphene Frameworks with Controllable C/O Ratios and Added Pseudocapacitances

3. Carbon-Based Supercapacitors Produced by Activation of Graphene

4. Nitrogen-doped mesoporous carbon of extraordinary capacitance for electrochemical energy storage

5. Graphene-based electrodes for electrochemical energy storage

Cited by 31 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Conversion of high moisture biomass to hierarchical porous carbon via molten base carbonisation and activation for electrochemical double layer capacitor;Bioresource Technology;2024-10

2. Unravelling K intercalation on graphene and its variants through two-dimensional cluster expansion modeling;Applied Surface Science;2024-08

3. Electron transition enhanced in-situ co-reduction mechanism enabling high-capacity and stable lithium storage for MoO3-x anode;Composites Part B: Engineering;2024-02

4. The impact of oxygen-clustering on the transformation of electrochemically-derived graphite oxide framework;Carbon;2024-01

5. Contribution of electron localization and delocalization zones in the performance of electrochemically reduced graphene oxide based supercapacitors: An experimental and the first-principles study;Carbon;2023-11