High-yield synthesis of a unique Mn(iii) siloxide complex through KMnO4 oxidation of a Mn(ii) precursor-Reference-Cited by-同舟云学术

High-yield synthesis of a unique Mn(iii) siloxide complex through KMnO4 oxidation of a Mn(ii) precursor

Published:2018 Issue:1 Volume:47 Page:62-66
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Lorenz Volker¹²³,Ehle Sophie¹²³,Liebing Phil⁴⁵⁶⁷^ORCID,Engelhardt Felix¹²³,Hashemi-Haeri Haleh⁸⁹¹⁰³,Oehler Florian⁸¹¹¹⁰³,Hinderberger Dariush⁸⁹¹⁰³^ORCID,Busse Sabine¹²³,Urbaschok Jens¹²³,Edelmann Frank T.¹²³^ORCID

Affiliation:

1. Chemisches Institut der Otto-von-Guericke-Universität

2. 39106 Magdeburg

3. Germany

4. ETH Zürich

5. Laboratorium für Anorganische Chemie

6. 8093 Zürich

7. Switzerland

8. Martin-Luther-Universität Halle-Wittenberg

9. Institut für Chemie – Physikalische Chemie

10. 06120 Halle (Saale)

11. Institut für Chemie – Anorganische Chemie

Abstract

A unique trivalent manganese siloxide complex, blue-violet Mn^IIILi₂Cl[(Ph₂SiO)₂O]₂(THF)₄·2THF (3) has been prepared by a straightforward two-step synthetic protocol.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C7DT03500D

Reference74 articles.

1. Chemistry of metallasiloxanes. Current trends and new concepts

2. Advances in Structurally Characterized Lanthanide Alkoxide, Aryloxide, and Silyloxide Compounds

3. Metalasiloxanes: New structure formation methods and catalytic properties

4. Disiloxanediolates and Metallasilsesquioxanes of the Rare Earth Elements

Cited by 3 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Evolution of Organometallasiloxanes;Высокомолекулярные соединения С;2023-12-01

2. Evolution of Organometallasiloxanes;Polymer Science, Series C;2023-11-15

3. Coordination chemistry of organometallic or inorganic binary group 14/16 units towards d-block and f-block metal atoms;Coordination Chemistry Reviews;2019-02