Enantioselective hydrogenation of cyclic imines catalysed by Noyori–Ikariya half-sandwich complexes and their analogues

Author:

Vilhanová B.1234,Václavík J.56784,Šot P.1234,Pecháček J.1234,Zápal J.9106711,Pažout R.12234,Maixner J.12234,Kuzma M.9106711,Kačer P.1234

Affiliation:

1. Department of Organic Technology

2. University of Chemistry and Technology

3. CZ-166 28 Prague

4. Czech Republic

5. Institute of Organic Chemistry and Biochemistry

6. v.v.i.

7. Academy of Sciences of the Czech Republic

8. CZ-166 10 Prague

9. Laboratory of Molecular Structure Characterization

10. Institute of Microbiology

11. CZ-142 20 Prague

12. Central Laboratories

Abstract

Trifluoroacetic acid activates cyclic imines in a new non-air sensitive asymmetric hydrogenation method. New transfer hydrogenation catalysts are demonstrated.

Funder

Czech Science Foundation

European Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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