A tetranuclear calcium hydride cluster with a highly symmetric [Ca4H6]2+ core-Reference-Cited by-同舟云学术

A tetranuclear calcium hydride cluster with a highly symmetric [Ca4H6]2+ core

Published:2019 Issue:98 Volume:55 Page:14837-14839
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Schuhknecht Danny¹²³⁴,Spaniol Thomas P.¹²³⁴,Douair Iskander⁵⁶⁷⁸⁹,Maron Laurent⁵⁶⁷⁸⁹^ORCID,Okuda Jun¹²³⁴^ORCID

Affiliation:

1. RWTH Aachen University

2. Institute of Inorganic Chemistry

3. 52056 Aachen

4. Germany

5. CNRS

6. INSA

7. UPS

8. UMR 5215

9. LPCNO

Abstract

The NNN-type macrocycle Me₃TACN stabilizes a highly symmetric calcium hydride with a tetranuclear [Ca₄H₆]²⁺ core. It can be classified as a nido-cluster with a highly delocalized system including d-orbital contribution.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC08540H

Reference30 articles.

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4. Rational Design of a Well-Defined Soluble Calcium Hydride Complex

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