Small iron–carbonyl clusters bearing imidazolium-2-trithioperoxycarboxylate ligands

Author:

Beltrán Tomás F.12345ORCID,Zaragoza Guillermo678910,Delaude Lionel12345ORCID

Affiliation:

1. Laboratory of Organometallic Chemistry and Homogeneous Catalysis

2. Institut de Chimie (B6a)

3. Allée du six Août 13

4. Quartier Agora

5. Université de Liège

6. Unidade de Difracción de Raios X

7. RIAIDT

8. Universidade de Santiago de Compostela

9. 15782 Santiago de Compostela

10. Spain

Abstract

The reaction of [Fe2(CO)9] with NHC·CS2zwitterions unexpectedly afforded two novel “sulfur-enriched” diiron hexacarbonyl clusters bearing imidazolium-2-trithioperoxycarboxylate ligands.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference54 articles.

1. An overview of N-heterocyclic carbenes

2. N-Heterocyclic Carbenes: Effective Tools for Organometallic Synthesis, ed. S. P. Nolan, Wiley-VCH, Weinheim, 2014

3. N-Heterocyclic Carbenes: From Laboratory Curiosities to Efficient Synthetic Tools, RSC Catalysis Series, ed. S. Díez-González, Royal Society of Chemistry, Cambridge, 2nd edn, 2017, vol. 27

4. Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes

5. N-Heterocyclic carbenes (NHCs) as organocatalysts and structural components in metal-free polymer synthesis

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