Oxidative dearomatisation: the key step of sorbicillinoid biosynthesis-Reference-Cited by-同舟云学术

Oxidative dearomatisation: the key step of sorbicillinoid biosynthesis

Published:2014 Issue:2 Volume:5 Page:523-527
ISSN:2041-6520
Container-title:Chem. Sci.
language:en
Short-container-title:Chem. Sci.

Author:

Fahad Ahmed al¹²³,Abood Amira¹²³⁴⁵,Fisch Katja M.¹²³,Osipow Anna¹²³,Davison Jack¹²³,Avramović Marija⁶⁷⁸,Butts Craig P.¹²³,Piel Jörn⁶⁷⁸⁹¹⁰,Simpson Thomas J.¹²³,Cox Russell J.¹²³¹¹¹²

Affiliation:

1. School of Chemistry

2. University of Bristol

3. Bristol BS8 1TS, UK

4. Chemistry of Natural and Microbial Products

5. National Research Centre

6. Institute of Microbiology

7. Eidgenössische Technische Hochschule (ETH) Zürich

8. 8093 Zürich, Switzerland

9. Kekulé Institute of Organic Chemistry and Biochemistry

10. University of Bonn

11. Institut für Organische Chemie

12. Leibniz Universität Hannover

Abstract

A new biosynthetic pathway to the sorbicillinoid natural products is proposed based on the observation of oxidative dearomatisation of dihydrosorbicillin 10b.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/SC/C3SC52911H

Reference31 articles.

1. The sorbicillinoid family of natural products: Isolation, biosynthesis, and synthetic studies

2. The biosynthesis of bisvertinolone: evidence for oxosorbicillinol as a direct precursor

3. Novel Oxidized Sorbicillin Dimers with 1,1-Diphenyl-2-picrylhydrazyl-Radical Scavenging Activity from a Fungus

4. Trisorbicillinone A, a novel sorbicillin trimer, from a deep sea fungus, Phialocephala sp. FL30r

5. The biosynthesis of sorbicillinoids in Trichoderma sp. USF-2690: prospect for the existence of a common precursor to sorbicillinol and 5-epihydroxyvertinolide, a new sorbicillinoid member

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