Transfer semi-hydrogenation of terminal alkynes with a well-defined iron complex-Reference-Cited by-同舟云学术

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Transfer semi-hydrogenation of terminal alkynes with a well-defined iron complex

Published:2024 Issue:8 Volume:53 Page:3484-3489
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Chowdhury Deep¹,Goswami Souvik¹,Krishna Gamidi Rama²^ORCID,Mukherjee Arup¹^ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Technology Bhilai, GEC Campus, Sejbahar, Raipur, Chhattisgarh 492015, India

2. Centre for X-ray Crystallography, CSIR-National Chemical Laboratory, Pune-411008, India

Abstract

A bench stable iron(ii) complex with the pincer ligand backbone was synthesized and characterized. The well-defined iron complex was successfully utilized for the dehydrogenation of DMAB and subsequent transfer semi-hydrogenation of terminal alkynes.

Funder

University Grants Commission

Science and Engineering Research Board

CouncilofScientific and Industrial Research, India

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D3DT03248E

Reference27 articles.

1. Living alkene polymerization: New methods for the precision synthesis of polyolefins

2. Stereoselective Semi‐Hydrogenations of Alkynes by First‐Row (3d) Transition Metal Catalysts

3. 3 d Transition Metal‐Catalyzed Hydrogenation of Nitriles and Alkynes

4. Efficient Z-Selective Semihydrogenation of Internal Alkynes Catalyzed by Cationic Iron(II) Hydride Complexes

5. Iron Catalysis in Reduction and Hydrometalation Reactions

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