Outer-sphere electron transfer does not underpin B12-dependent olefinic reductive dehalogenation in anaerobes

Author:

Zhang Shangwei12ORCID,Adrian Lorenz34ORCID,Schüürmann Gerrit25ORCID

Affiliation:

1. Environmental Microbiomics Research Center, School of Environmental Science and Engineering, Guangdong Provincial Key Laboratory of Environmental Pollution Control and Remediation Technology, Southern Marine Science and Engineering Guangdong Laboratory (Zhuhai), Sun Yat-Sen University, Guangzhou 510006, China

2. UFZ Department of Ecological Chemistry, Helmholtz Centre for Environmental Research, Permoserstraße 15, Leipzig 04318, Germany

3. UFZ Department of Environmental Biotechnology, Helmholtz Centre for Environmental Research, Permoserstraße 15, 04318 Leipzig, Germany

4. Chair of Geobiotechnology, Technische Universität Berlin, Ackerstraße 76, 13355 Berlin, Germany

5. Technical University Bergakademie Freiberg, Institute of Organic Chemistry, Leipziger Straße 29, 09596 Freiberg, Germany

Abstract

Outer-sphere electron transfer does not underpin microbial B12-dependent olefinic reductive dehalogenation.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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