Redox insights and OER activity in 3D-MOFs: the role of alkali metal ions

Author:

Dinda Susanta1ORCID,Karmakar Arun23ORCID,Ghoshal Debajyoti1ORCID,Kundu Subrata23ORCID

Affiliation:

1. Department of Chemistry, Jadavpur University, Jadavpur, Kolkata-700032, India

2. Academy of Scientific and Innovative Research (AcSIR), Ghaziabad-201002, India

3. Materials Chemistry Laboratory for Energy, Environment and Catalysis, Electrochemical Process Engineering (EPE) Division, CSIR-Central Electrochemical Research Institute (CECRI), Karaikudi-630003, Tamil Nadu, India

Abstract

In situ decoration of outer sphere K+ ions was made in a 3D Co(ii) MOFs, those are showing outstanding OER activity; having 27-fold higher TOF than Co3O4 materials. The impact of K+ ions was examined through various electrochemical studies, marking first instance of such an investigation.

Funder

Science and Engineering Research Board

Central ElectroChemical Research Institute

Department of Science and Technology, Ministry of Science and Technology, India

Publisher

Royal Society of Chemistry (RSC)

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