Facilitated explosion of nitro compounds confined in metal–organic frameworks

Author:

Kim Eun-Young12,Han Mingu3,Kim Seong Han3,Joe Hye Jung45,Kim Seok Ki45,Bae Youn-Sang2ORCID,Moon Su-Young1ORCID

Affiliation:

1. C1 Gas & Carbon Convergent Research Center, Chemical & Process Technology, Korea Research Institute of Chemical Technology, Daejeon 34114, Korea

2. Department of Chemical and Biomolecular Engineering Technology, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul 03722, Korea

3. 1st R&D Institute 2nd Directorate, Agency for Defense Development, Yuseong, P. O. Box 35-42, Daejeon 34186, Korea

4. Department of Chemical Engineering, Ajou University, Suwon 16499, Korea

5. Department of Energy Systems Research, Ajou University, Suwon 16499, Korea

Abstract

TNT@MOF was prepared by confining 2,4,6-trinitrotoluene (TNT) into a Cr-based metal–organic framework (MOF). Compared with raw TNT, the initiation activity of TNT@MOF was enhanced due to the interplay between the nitro group of TNT and the CUS of MOFs.

Funder

Defense Acquisition Program Administration

Ministry of National Defense

Publisher

Royal Society of Chemistry (RSC)

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