Epitaxial stabilization versus interdiffusion: synthetic routes to metastable cubic HfO2 and HfV2O7 from the core–shell arrangement of precursors-Reference-Cited by-同舟云学术

Epitaxial stabilization versus interdiffusion: synthetic routes to metastable cubic HfO2 and HfV2O7 from the core–shell arrangement of precursors

Published:2019 Issue:44 Volume:11 Page:21354-21363
ISSN:2040-3364
Container-title:Nanoscale
language:en
Short-container-title:Nanoscale

Author:

Fleer Nathan A.¹²³⁴⁵,Thomas Melonie P.¹⁶⁷⁴^ORCID,Andrews Justin L.¹²³⁴⁵,Waetzig Gregory R.¹²³⁴⁵,Gonzalez Oscar¹²³⁴,Liu Guan-Wen¹²³⁴⁵,Guiton Beth S.¹⁶⁷⁴^ORCID,Banerjee Sarbajit¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Texas A&M University

3. College Station

4. USA

5. Department of Materials Science and Engineering

6. University of Kentucky

7. Lexington

Abstract

Metastable cubic HfO₂ is prepared by preferential nucleation using a lattice crystallographic relationship.

Funder

National Science Foundation

Kentucky Space Grant Consortium

Welch Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

Link

http://pubs.rsc.org/en/content/articlepdf/2019/NR/C9NR07316G

Reference54 articles.

1. Nanoscale Effects on Thermodynamics and Phase Equilibria in Oxide Systems

2. Toward Reaction-by-Design: Achieving Kinetic Control of Solid State Chemistry with Metathesis

3. Traversing Energy Landscapes Away from Equilibrium: Strategies for Accessing and Utilizing Metastable Phase Space

4. The thermodynamic scale of inorganic crystalline metastability

5. Real-time atomistic observation of structural phase transformations in individual hafnia nanorods

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