Copper-catalyzed crosscoupling of vinyl nitrenes and CF<sub>3</sub>-carbenes to synthesize CF<sub>3</sub>-2-azadienes-Reference-Cited by-同舟云学术

Copper-catalyzed crosscoupling of vinyl nitrenes and CF₃-carbenes to synthesize CF₃-2-azadienes

Published:2024 Issue:1 Volume:11 Page:67-73
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Jiao Yongjuan¹,Wu Tao¹,Zhang Xinyu¹,Jiang Yaojia¹²^ORCID

Affiliation:

1. Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, China

2. Laboratory Breeding Base of Green Pesticide and Agricultural Bioengineering, Key Laboratory of Green Pesticide and Agricultural Bioengineering Ministry of Education, Guizhou University, Huaxi, Guiyang 550025, China

Abstract

A unique and efficient copper catalytic system has been established for the synthesis of fluorinated 2-azadienes from isoxazoles and CF3-N-tosylhydrazones via crosscoupling reactions of vinyl nitrenes with fluoroalkyl carbenes.

Funder

Guizhou University

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QO/D3QO01537H

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4. Recent progress on donor and donor–donor carbenes

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