Spectroscopic signatures of ligand field states in {RuII(imine)} complexes
Author:
Affiliation:
1. Departamento de Química Analítica
2. Inorgánica y Química Física
3. INQUIMAE
4. Facultad de Ciencias Exactas y Naturales
5. Universidad de Buenos Aires
6. Department of Chemistry and Biochemistry
7. University of Notre Dame
8. Notre Dame
9. USA
Abstract
Clear spectroscopic signatures of ligand field states in the MLCT decay cascade of trans-[Ru(L)4(NCS)2] (L = pyridine or 4-methoxypyridine) were found. (TD)DFT calculations reveal the presence of both MLCT and LMCT transient absorption bands.
Funder
National Science Foundation
Universidad de Buenos Aires
Consejo Nacional de Investigaciones Científicas y Técnicas
Agencia Nacional de Promoción Científica y Tecnológica
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT04332H
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