Spectroscopic signatures of ligand field states in {RuII(imine)} complexes-Reference-Cited by-同舟云学术

Spectroscopic signatures of ligand field states in {RuII(imine)} complexes

Published:2016 Issue:13 Volume:45 Page:5464-5475
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Cadranel Alejandro¹²³⁴⁵,Pieslinger German E.¹²³⁴⁵^ORCID,Tongying Pornthip⁶⁷⁸⁹,Kuno Masaru K.⁶⁷⁸⁹,Baraldo Luis M.¹²³⁴⁵,Hodak José H.¹²³⁴⁵

Affiliation:

1. Departamento de Química Analítica

2. Inorgánica y Química Física

3. INQUIMAE

4. Facultad de Ciencias Exactas y Naturales

5. Universidad de Buenos Aires

6. Department of Chemistry and Biochemistry

7. University of Notre Dame

8. Notre Dame

9. USA

Abstract

Clear spectroscopic signatures of ligand field states in the MLCT decay cascade of trans-[Ru(L)₄(NCS)₂] (L = pyridine or 4-methoxypyridine) were found. (TD)DFT calculations reveal the presence of both MLCT and LMCT transient absorption bands.

Funder

National Science Foundation

Universidad de Buenos Aires

Consejo Nacional de Investigaciones Científicas y Técnicas

Agencia Nacional de Promoción Científica y Tecnológica

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT04332H

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