A combined density functional theory and numerical simulation investigation of levels of chirality transfer and regioselectivity for the radical cyclizations of N-methyl-, N-ethyl- and N-isopropyl-substituted ortho-halo-N-acryloylanilides-Reference-Cited by-同舟云学术

A combined density functional theory and numerical simulation investigation of levels of chirality transfer and regioselectivity for the radical cyclizations of N-methyl-, N-ethyl- and N-isopropyl-substituted ortho-halo-N-acryloylanilides

Published:2018 Issue:12 Volume:42 Page:9783-9790
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Wang Xiao-xu¹²³⁴⁵,Yuan Lang¹²³⁴⁵,Jia Cai-xin¹²³⁴⁵,Qu Hong-jie¹²³⁴⁵,Li Bai-jian¹²³⁴⁵,Chi Yu-juan¹²³⁴⁵,Yu Hai-tao¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory of Functional Inorganic Material Chemistry (Ministry of Education of China)

2. School of Chemistry and Materials Science

3. Heilongjiang University

4. Harbin 150080

5. China

Abstract

There is a high chirality transfer ratio when the N-alkyl substituent is larger in volume than isopropyl.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C8NJ01102H

Reference102 articles.

1. Free radical-mediated ring expansion and related annulations

2. Free radical cyclizations involving nitrogen

3. Programming Organic Molecules: Design and Management of Organic Syntheses through Free-Radical Cascade Processes

4. Stereoselective radical reactions

5. Formation of five- and six-membered heterocyclic rings under radical cyclisation conditions

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