Synthesis and ligand substitution reactions of κ4-B,S,S′,S′′-ruthenaboratranes-Reference-Cited by-同舟云学术

Synthesis and ligand substitution reactions of κ4-B,S,S′,S′′-ruthenaboratranes

Published:2019 Issue:1 Volume:48 Page:209-219
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Foreman Mark R. St.-J.¹²³⁴⁵^ORCID,Hill Anthony F.⁶⁷⁸⁹^ORCID,Ma Chenxi⁶⁷⁸⁹,Tshabang Never⁶⁷⁸⁹¹⁰,White Andrew J. P.¹¹¹⁰¹²¹³

Affiliation:

1. Department of Chemistry and Chemical Engineering

2. Nuclear Chemistry and Industrial Materials Recycling

3. Chalmers University of Technology

4. Göteborg

5. Sweden

6. Research School of Chemistry

7. Australian National University

8. Canberra

9. Australia

10. Department of Chemistry

11. Chemical Crystallography Laboratory

12. Imperial College London White City Campus

13. UK

Abstract

Ruthenaboratranes of the form [Ru(CO)L{κ⁴-B(mt)₃}] (mt = N-methimazolyl) arise via substitution of the PPh₃ ligand in [Ru(CO)(PPh₃){κ⁴-B(mt)₃}] by L (L = PMe₂Ph, PMe₃, P(OMe)₃, P(OEt)₃, P(OPh)₃) or reactions of [RuCl(R)(CO)L_n] (R = Ph, CHCHPh; n = 2, L = PCy₃; n = 3, L = P(OMe)₃, PMe₂Ph) with Na[HB(mt)₃].

Funder

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT04278K

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