Bi-stable spin-crossover in charge-neutral [Fe(R-ptp)2] (ptp = 2-(1H-pyrazol-1-yl)-6-(1H-tetrazol-5-yl)pyridine) complexes-Reference-Cited by-同舟云学术

Bi-stable spin-crossover in charge-neutral [Fe(R-ptp)2] (ptp = 2-(1H-pyrazol-1-yl)-6-(1H-tetrazol-5-yl)pyridine) complexes

Published:2020 Issue:4 Volume:49 Page:1022-1031
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Senthil Kumar Kuppusamy¹²³⁴^ORCID,Vela Sergi⁵⁶⁷⁸⁴^ORCID,Heinrich Benoît¹²³⁴^ORCID,Suryadevara Nithin⁹¹⁰¹¹¹²¹³,Karmazin Lydia¹⁴¹⁵¹⁶¹⁷⁴^ORCID,Bailly Corinne¹⁴¹⁵¹⁶¹⁷⁴,Ruben Mario¹²³⁴⁹^ORCID

Affiliation:

1. Institut de Physique et Chimie des Matériaux de Strasbourg (IPCMS)

2. CNRS-Université de Strasbourg

3. 67034 Strasbourg Cedex 2

4. France

5. Laboratoire de Chimie Quantique

6. Institut de Chimie

7. UMR 7177 CNRS-Université de Strasbourg

8. 67081 Strasbourg

9. Institute of Nanotechnology (INT)

10. Karlsruhe Institute of Technology (KIT)

11. Hermann-von-Helmholtz-Platz 1

12. Eggenstein-Leopoldshafen

13. Germany

14. Service de Radiocristallographie

15. Fédération de Chimie Le Bel

16. FR2010 CNRS-Université de Strasbourg

17. 67008 Strasbourg Cedex

Abstract

Factors controlling spin-crossover (SCO) in charge-neutral [Fe(R-ptp)₂]⁰ complexes composed of rationally designed 2-(1H-pyrazol-1-yl)-6-(1H-tetrazol-5-yl)pyridine (ptp)-based ligands are elucidated.

Funder

Fédération pour la Recherche sur le Cerveau

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/C9DT04411F

Reference87 articles.

1. A spin transition system with a thermal hysteresis at room temperature

2. Abrupt spin transition around room temperature and light induced properties in FeII complexes with N4O2 coordination sphere