Principles of melting in hybrid organic–inorganic perovskite and polymorphic ABX<sub>3</sub> structures-Reference-Cited by-同舟云学术

Principles of melting in hybrid organic–inorganic perovskite and polymorphic ABX₃ structures

Published:2022 Issue:7 Volume:13 Page:2033-2042
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Shaw Bikash Kumar¹^ORCID,Castillo-Blas Celia¹²,Thorne Michael F.¹^ORCID,Ríos Gómez María Laura¹,Forrest Tom³,Lopez Maria Diaz³,Chater Philip A.³^ORCID,McHugh Lauren N.¹^ORCID,Keen David A.⁴^ORCID,Bennett Thomas D.¹^ORCID

Affiliation:

1. Department of Materials Science and Metallurgy, University of Cambridge, CB3 0FS, UK

2. Departamento de Química Inorgánica, Universidad Autónoma de Madrid, 28049 Madrid, Spain

3. Diamond Light Source Ltd, Diamond House, Harwell Campus, Didcot, Oxfordshire, OX11 0DE, UK

4. ISIS Facility, Rutherford Appleton Laboratory, Harwell Campus, Didcot, Oxfordshire, OX11 0QX, UK

Abstract

Increasing the size of the A-site cation from (C3H7)4N → (C4H9)4N → (C5H11)4N in hybrid organic–inorganic ABX3 structures was observed to result in a decrease in Tm, through an increase in ΔSf.

Funder

Royal Society

Science and Engineering Research Board

European Social Fund

University of Cambridge

Leverhulme Trust

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D1SC07080K