Novel approach to benzo-fused 1,2-azaphospholene involving a Pd(ii)-assisted tandem P–C bond cleavage and P–N bond formation reaction-Reference-Cited by-同舟云学术

Novel approach to benzo-fused 1,2-azaphospholene involving a Pd(ii)-assisted tandem P–C bond cleavage and P–N bond formation reaction

Published:2021 Issue:39 Volume:57 Page:4835-4838
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Kunchur Harish S.¹²³⁴⁵,Radhakrishna Latchupatula¹²³⁴⁵,Pandey Madhusudan K.¹²³⁴⁵^ORCID,Balakrishna Maravanji S.¹²³⁴⁵^ORCID

Affiliation:

1. Phosphorus Laboratory

2. Department of Chemistry

3. Indian Institute of Technology Bombay

4. Powai

5. India

Abstract

Pd(ii) assisted P–C/Pd–C bond metathesis was observed in the reaction of amide based bisphoshine (Bala-HariPhos). The cleavage of P–Ph with the elimination of PhH to form a new P–N bond, resulting in a 1,2-azaphospholene ring.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC01591E

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