Hydrogen abstraction from organotin di- and trihydrides by N-heterocyclic carbenes: a new method for the preparation of NHC adducts to tin(ii) species and observation of an isomer of a hexastannabenzene derivative [R6Sn6]-Reference-Cited by-同舟云学术

Hydrogen abstraction from organotin di- and trihydrides by N-heterocyclic carbenes: a new method for the preparation of NHC adducts to tin(ii) species and observation of an isomer of a hexastannabenzene derivative [R6Sn6]

Published:2014 Issue:7 Volume:5 Page:2739-2746
ISSN:2041-6520
Container-title:Chem. Sci.
language:en
Short-container-title:Chem. Sci.

Author:

Sindlinger Christian P.¹²,Wesemann Lars¹²

Affiliation:

1. Institut für Anorganische Chemie der Universität Tübingen

2. 72076 Tübingen, Germany

Abstract

N-Heterocyclic carbenes are shown to cleanly abstract dihydrogen from organotin di- and trihydrides to intermediately form the reactive stannylene species [R₂Sn] and [R′SnH], respectively, which undergo further reactions.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/SC/C4SC00365A

Reference67 articles.

1. Tri-n-butyltin Hydride as Reagent in Organic Synthesis

2. A. G. Davies , Organotin Chemistry, Wiley-VCH Verlag GmbH & Co. KGaA, 2004

3. A convenient route to distannanes, oligostannanes, and polystannanes

4. Facile synthesis of linear poly(dibutylstannane)

5. From poly(dialkylstannane)s to poly(diarylstannane)s: comparison of synthesis methods and resulting polymers

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