DFT studies on the mechanism of palladium-catalyzed carbon–silicon cleavage for the synthesis of benzosilole derivatives-Reference-Cited by-同舟云学术

DFT studies on the mechanism of palladium-catalyzed carbon–silicon cleavage for the synthesis of benzosilole derivatives

Published:2014 Issue:29 Volume:43 Page:11138-11144
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Chen Wen-Jie¹²³,Lin Zhenyang¹²³

Affiliation:

1. Department of Chemistry

2. The Hong Kong University of Science and Technology

3. , People's Republic of China

Abstract

DFT calculations have been carried out to study the detailed mechanism of Pd-catalyzed intermolecular coupling reactions of 2-silylaryl bromides with alkynes via selective cleavage of C(sp³)–Si bonds.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C3DT53391C

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