Oxyallyl cation promoted dearomative semipinacol rearrangement: a facile stereodivergent synthesis of spiro-indolines with contiguous quaternary centers-Reference-Cited by-同舟云学术

Oxyallyl cation promoted dearomative semipinacol rearrangement: a facile stereodivergent synthesis of spiro-indolines with contiguous quaternary centers

Published:2021 Issue:54 Volume:57 Page:6632-6635
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Xie Yu-Yang¹²³⁴⁵,Wang Yun-Peng¹²³⁴⁵,Zhao Xiao-Jing¹²³⁴⁵,Wang Ai-Fang¹²³⁴⁵,Chen Zhi-Min¹²³⁴⁵^ORCID,Tu Yong-Qiang¹²³⁴⁵^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering

2. Shanghai Key Laboratory for Molecular Engineering of Chiral Drugs

3. Frontiers Science Center for Transformative Molecules

4. Shanghai Jiao Tong University

5. Shanghai

Abstract

A novel oxyallyl cation promoted semipinacol rearrangement of indole-type allylic alcohols was disclosed for the stereo-divergent synthesis of spiro-indolines.

Funder

National Natural Science Foundation of China

Science and Technology Commission of Shanghai Municipality

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC02033A

Reference47 articles.

1. Indoles in Multicomponent Processes (MCPs)

2. Transition Metal-Catalyzed CH Activation of Indoles

3. Rings in Drugs

4. Intramolecular Dearomative Oxidative Coupling of Indoles: A Unified Strategy for the Total Synthesis of Indoline Alkaloids

5. A Radical Cascade Enabling Collective Syntheses of Natural Products

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