Structural analysis of five-coordinate aluminium(salen) complexes and its relationship to their catalytic activity

Author:

Fish Heather1234,Hart Sam1234,Lamb Katie J.1234ORCID,North Michael1234ORCID,Quek Sophie C. Z.1234,Whitwood Adrian C.1234ORCID,Woods Barnaby1234,Wu Xiao1234

Affiliation:

1. Department of Chemistry

2. University of York

3. Heslington

4. UK

Abstract

Five-coordinate aluminium(salen) complexes have dynamic structures which interconvert by intramolecular salen ligand rearrangement involving square-based pyramidal and trigonal bipyramidal conformations.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference39 articles.

1. Privileged Chiral Ligands and Catalysts , ed. Q.-L. Zhou , Wiley-VCH , Weinheim , 2011 , ch. 7

2. Catalytic activities of Schiff base transition metal complexes

3. S. Bellemin-Laponnaz and S.Dagorne , Coordination Chemistry and Applications of Salen, Salan and Salalen Metal Complexes , in Pata's Chemistry of Functional Groups (Metal phenolates) , Wiley-VCH , 2012 , pp. 263–309

4. Al(Salen) Metal Complexes in Stereoselective Catalysis

5. Influence of the metal and chiral diamine on metal(II)salen catalysed, asymmetric synthesis of α-methyl α-amino acids

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