Cu<sub>12</sub>-cluster-based metal–organic framework as a metastable intermediate in the formation of a layered copper phosphonate-Reference-Cited by-同舟云学术

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Cu₁₂-cluster-based metal–organic framework as a metastable intermediate in the formation of a layered copper phosphonate

Published:2024 Issue:60 Volume:60 Page:7765-7768
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Teng Qian¹,Gao Ran¹,Bao Song-Song¹^ORCID,Zheng Li-Min¹^ORCID

Affiliation:

1. State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, P. R. China

Abstract

The solvothermal reaction of CuSO4·5H2O and a chiral R-pempH2 ligand (molar ratio 6 : 1) first forms a metastable intermediate [Cu24(OH)20(R-pempH)8(SO4)10·(H2O)10.5]·35H2O (1), then a stable phase [Cu2(OH)(R-pempH)(SO4)(H2O)]·H2O (2).

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC00550C

Reference28 articles.

1. Understanding the Synthesis Kinetics of Single‐Crystal Co‐Free Ni‐Rich Cathodes

2. Layer-by-layer evolution and a hysteretic single-crystal to single-crystal transformation cycle of a flexible pillared-layer open framework

3. Isolation of a Metastable Intermediate in a Heterometallic CuII–HgII 1D Polymeric Chain: Synthesis, Crystal Structure, and Photophysical Properties

4. Linker Deprotonation and Structural Evolution on the Pathway to MOF-74

5. Kinetic Trapping of Photoluminescent Frameworks During High-Concentration Synthesis of Nonemissive Metal–Organic Frameworks

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