The group 9 cyclopentadienylmetal cis-ethylenedithiolates as metallodithiolene ligands in metal carbonyl chemistry: analogies to benzene metal carbonyl complexes

Author:

Radu Luana-Flavia1234,Attia Amr A. A.1234,Silaghi-Dumitrescu Radu1234ORCID,Lupan Alexandru1234,King R. Bruce5678ORCID

Affiliation:

1. Faculty of Chemistry and Chemical Engineering

2. Babeş-Bolyai University

3. Cluj-Napoca

4. Romania

5. Department of Chemistry

6. University of Georgia

7. Athens

8. USA

Abstract

The species CpMS2C2H2 (M = Co, Rh, Ir) are aromatic systems that can function as pentahapto six-electron metallodithiolene ligands through all five atoms of their MS2C2 rings as in the lowest energy heterobimetallic complexes CpMS2C2H2·Cr(CO)n (n = 3, 2) and CpMS2C2H2·Fe(CO)2.

Funder

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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