Redox chemistry of a binary transition metal oxide (AB2O4): a study of the Cu2+/Cu0 and Fe3+/Fe0 interconversions observed upon lithiation in a CuFe2O4 battery using X-ray absorption spectroscopy
Author:
Affiliation:
1. Department of Chemistry
2. Stony Brook University
3. Stony Brook
4. USA
5. Energy Sciences Directorate
6. Brookhaven National Laboratory
7. Upton
8. Department of Materials Science and Engineering
Abstract
The first XAS study of (de)lithiation of CuFe2O4 showed iron can be reoxidized while Cu0 remains in its reduced form.
Funder
Basic Energy Sciences
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP02974D
Reference41 articles.
1. 57Fe Mössbauer Spectroscopy and Electron Microscopy Study of Metal Extraction from CuFe2O4 Electrodes in Lithium Cells
2. Electrochemical evaluation of CuFe2O4 samples obtained by sol–gel methods used as anodes in lithium batteries
3. CuFe2O4/SnO2 nanocomposites as anodes for Li-ion batteries
4. Hollow CuFe2O4 spheres encapsulated in carbon shells as an anode material for rechargeable lithium-ion batteries
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