High adsorption of ammonia in a titanium-based metal–organic framework-Reference-Cited by-同舟云学术

High adsorption of ammonia in a titanium-based metal–organic framework

Published:2024 Issue:46 Volume:60 Page:5912-5915
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Zeng Xiangdi¹,Li Jiangnan¹²,He Meng¹^ORCID,Lu Wanpeng¹,Crawshaw Danielle¹^ORCID,Guo Lixia¹²,Ma Yujie¹^ORCID,Kippax-Jones Meredydd¹³,Cheng Yongqiang⁴,Manuel Pascal⁵,Rudić Svemir⁵^ORCID,Frogley Mark D.³^ORCID,Schröder Martin¹^ORCID,Yang Sihai¹²^ORCID

Affiliation:

1. Department of Chemistry, University of Manchester, Manchester, M13 9PL, UK

2. College of Chemistry and Molecular Engineering, Beijing National Laboratory for Molecular Sciences, Peking University, Beijing, 100871, China

3. Diamond Light Source, Harwell Science Campus, Oxfordshire, OX11 0DE, UK

4. Neutron Scattering Division, Neutron Sciences Directorate, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA

5. ISIS Neutron and Muon Facility, Rutherford Appleton Laboratory, Didcot, OX11 0QX, UK

Abstract

A robust titanium-based metal–organic framework, MFM-300(Ti), exhibits an exceptional NH3 adsorption of 23.4 mmol g−1 with a record-high packing density of 0.84 g cm−3, promoted by strong binding interactions of NH3 to the framework oxygen sites.

Funder

Beijing National Laboratory for Molecular Sciences

Engineering and Physical Sciences Research Council

National Natural Science Foundation of China

Horizon 2020

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC01449A

Reference15 articles.

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2. A Roadmap to the Ammonia Economy

3. Comparison of sorbents and isotherm models for NH3-gas separation by adsorption

4. MCM-41 impregnated with active metal sites: Synthesis, characterization, and ammonia adsorption