Low temperature aging in a molecular glass: the case of cis-methyl formate-Reference-Cited by-同舟云学术

Low temperature aging in a molecular glass: the case of cis-methyl formate

Published:2021 Issue:29 Volume:23 Page:15719-15726
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Cassidy Andrew¹²³⁴^ORCID,Jørgensen Mads R. V.⁵⁶²³⁴^ORCID,Glavic Artur⁷⁸⁹¹⁰^ORCID,Lauter Valeria¹¹¹²¹³¹⁴^ORCID,Plekan Oksana¹⁵¹⁶¹⁷¹⁸^ORCID,Field David¹²³⁴^ORCID

Affiliation:

1. Center for Interstellar Catalysis and Department of Physics and Astronomy

2. Aarhus University

3. Aarhus C

4. Denmark

5. Center of Materials Crystallography

6. iNano & Department of Chemistry

7. Laboratory for Neutron and Muon Instrumentation

8. Paul Scherrer Institut

9. 5232 Villigen PSI

10. Switzerland

11. Neutron Scattering Division

12. Oak Ridge National Lab

13. Oak Ridge

14. USA

15. Sincrotrone Trieste S.C.P.A.

16. Area Science Park

17. I-34149 Basovizza, Trieste

18. Italy

Abstract

The spontaneously generated electric field in a molecular glass, decays with time at deeply supercooled temperatures. Here, we fit the rate of decay with a model to extract the activation barrier to molecular rotation, as the glass ages.

Funder

Danmarks Grundforskningsfond

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP01332G

Reference31 articles.

1. Relaxation and physical aging in network glasses: a review

2. Introduction: Organic Electronics and Optoelectronics

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