Energetic pathways and influence of the metallacyclobutane intermediates formed during isobutene/2-butene cross-metathesis over WH3/Al2O3 supported catalyst-Reference-Cited by-同舟云学术

Energetic pathways and influence of the metallacyclobutane intermediates formed during isobutene/2-butene cross-metathesis over WH3/Al2O3 supported catalyst

Published:2016 Issue:10 Volume:6 Page:3386-3393
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Motta A.¹²³⁴,Szeto K. C.⁵⁶⁷⁸⁹,Taoufik M.⁵⁶⁷⁸⁹,Nicholas C. P.¹⁰¹¹¹²¹³

Affiliation:

1. Dipartimento di Chimica and INSTM UdR Roma

2. Università degli Studi di Roma “La Sapienza” P.le A. Moro 5

3. Roma

4. Italy

5. Laboratoire de Chimie Organométallique de Surface

6. Université Lyon 1

7. C2P2

8. CNRS UMR 5265

9. ICL

10. Exploratory Catalysis Research

11. UOP LLC

12. Des Plaines

13. USA

Abstract

The preferred catalytic cycle occurring in the conversion of isobutene and 2-butene to propylene and pentenes over WH₃/Al₂O₃ has been investigated via an energetic analysis of the metallacyclobutanes formed upon 2 + 2 butene cycloaddition with alumina supported tungsten alkylidenes.

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CY/C5CY02154E

Reference39 articles.

1. Olefin metathesis - A novel reaction for skeletal transformations of unsaturated hydrocarbons

2. Industrial applications of olefin metathesis

3. Olefin Disproportionation. A New Catalytic Process

4. Olefin Metathesis Theory and Practice, ed. K. Grela, Wiley, 2014

5. Olefin Metathesis by Supported Metal Oxide Catalysts

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