On the dual reactivity of a Janus-type mesoionic dipole: experiments and theoretical validation-Reference-Cited by-同舟云学术

On the dual reactivity of a Janus-type mesoionic dipole: experiments and theoretical validation

Published:2018 Issue:26 Volume:16 Page:4778-4783
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

de la Concepción Juan García¹²³⁴⁵^ORCID,Ávalos Martín¹²³⁴⁵^ORCID,Cintas Pedro¹²³⁴⁵^ORCID,Jiménez José L.¹²³⁴⁵^ORCID,Light Mark E.⁶⁷⁸⁹^ORCID

Affiliation:

1. Departamento de Química Orgánica e Inorgánica

2. Facultad de Ciencias-UEX

3. IACYS-Unidad de Química Verde y Desarrollo Sostenible

4. E-06006 Badajoz

5. Spain

6. Department of Chemistry

7. University of Southampton

8. Southampton SO17 1BJ

9. UK

Abstract

A mesoionic bicycle, easily synthesized from a proteinogenic amino acid, l-leucine, behaves as both thiazolium-olate and diazolium-olate dipoles, as unveiled by its dipolar cycloadditions.

Funder

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/OB/C8OB01195H

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