Deciphering crystal packing effects in the spin crossover of six [FeII(2-pic)3]Cl2 solvatomorphs-Reference-Cited by-同舟云学术

Deciphering crystal packing effects in the spin crossover of six [FeII(2-pic)3]Cl2 solvatomorphs

Published:2019 Issue:4 Volume:48 Page:1237-1245
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Vela Sergi¹²³⁴⁵^ORCID,Paulsen Hauke⁶⁷⁸⁹

Affiliation:

1. Laboratoire de Chimie Quantique

2. UMR 7111

3. CNRS-Université de Strasbourg

4. F-67000 Strasbourg

5. France

6. Institut für Physik

7. Universität zu Lübeck

8. D-23562 Lübeck

9. Germany

Abstract

Six isostructural solvatomorphs of the same Fe(ii) complex have been reported to display completely different SCO transitions due to tiny differences in their crystal environments. In this paper, we unravel the reasons.

Funder

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT04394A

Reference62 articles.

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