Deprotonation/protonation-driven change of the σ-donor ability of a sulfur atom in iron(ii) complexes with a thioamide SNS pincer type ligand
Author:
Affiliation:
1. Department of Frontier Materials
2. Graduate School of Engineering
3. Nagoya Institute of Technology
4. Nagoya 466-8555, Japan
5. Department of Applied Chemistry
6. Aichi Institute of Technology
7. Toyota 470-0392, Japan
Abstract
A new iron complex with a thioamide SNS pincer type ligand, [FeBr2(κ3-H2LDPM)] (κ3-H2LDPM = 2,6-bis(N-2,6-bis(diphenylmethyl)-4-isopropylphenylthioamide)pyridine), was synthesized.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT00524D
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