Water is a key factor to alter the structure and electrochemical properties of carboxylate-bridged dimanganese(ii) complexes-Reference-Cited by-同舟云学术

Water is a key factor to alter the structure and electrochemical properties of carboxylate-bridged dimanganese(ii) complexes

Published:2014 Issue:30 Volume:43 Page:11465-11469
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Sivanesan Dharmalingam¹²³⁴,Kannan Sethuraman¹²³⁴,Thangadurai Thangaian Daniel¹²³⁴,Jung Kwang-Deog⁵⁴,Yoon Sungho¹²³⁴

Affiliation:

1. Department of Bio & Nano Chemistry

2. College of Natural Sciences

3. Kookmin University

4. Seongbuk-gu, Republic of Korea

5. Clean Energy Research Center Korea Institute of Science and Technology

Abstract

The three manganese complexes with the {Mn₂(μ-O₂CR)}³⁺, {Mn₂(μ-OH₂)₂(μ-O₂CR)}³⁺, and {Mn₂(OH₆)₂(O₂CR)}³⁺motifs are in dynamic equilibrium, displaying significantly different electrochemical properties ranging from 0.52 V to 1.19 Vvs.Fc/Fc⁺.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT00520A

Reference31 articles.

1. Manganese Enzymes with Binuclear Active Sites

2. Recent advances in the understanding of the biological chemistry of manganese

3. Dinuclear Mn complexes as functional models of Mn catalase

4. Structural, Spectroscopic, and Reactivity Models for the Manganese Catalases

5. Carboxylate-bridged dinuclear manganese systems – From catalases to oxidation catalysis

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