Binary lanthanide(iii)/nitrate and ternary lanthanide(iii)/nitrate/chloride complexes in an ionic liquid containing water: optical absorption and luminescence studies

Author:

Ansari Seraj A.12345,Liu Lisheng12346,Rao Linfeng1234

Affiliation:

1. Chemical Sciences Division

2. Lawrence Berkeley National Laboratory

3. Berkeley

4. USA

5. Radiochemistry Division

6. Department of Radiochemistry

Abstract

Thermodynamic and spectroscopic data indicate that nitrate and chloride are stronger ligands than water for lanthanides in water saturated BumimTf2N.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference46 articles.

1. Lanthanides and Actinides in Ionic Liquids

2. Actinide Chemistry in Ionic Liquids

3. Room-Temperature Ionic Liquids. Solvents for Synthesis and Catalysis

4. I. Billard , Ionic liquids: New hopes for efficient lanthanide/actinide extraction and separation, in Handbook on the Physics and Chemistry of Rare Earths, ed. J. C. G. Bunzli and V. Pecharsky, Elsevier Science Pub. B.V., Amsterdam, 2013

5. Ionic Liquids-Based Extraction: A Promising Strategy for the Advanced Nuclear Fuel Cycle

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