Cation–anion confined hydrogen-bonding catalysis strategy for ring-closing C–O/O–H metathesis of alkoxy alcohols under metal-free conditions

Author:

Wang Huan12,Zhao Zhi-Hao13,Zhao Yanfei14,Zhang Fengtao14,Xiang Junfeng1,Han Buxing14ORCID,Liu Zhimin14ORCID

Affiliation:

1. Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid and Interface and Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

2. College of Chemistry & Chemical Engineering, Shaanxi Key Laboratory of Chemical Additives for Industry, Shaanxi University of Science & Technology, Xi'an, Shaanxi, 710021, China

3. State Key Laboratory of Solidification Processing and School of Materials Science and Engineering, Northwestern Polytechnical University, Xi'an, Shaanxi, 710072, P. R. China

4. University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

Cation–anion confined hydrogen-bonding-catalyzed ring-closing C–O/O–H metathesis of alkoxy alcohols to O-heterocycles is realized over OH-functionalized ionic liquids under metal-free and mild conditions (≥70 °C).

Funder

Natural Science Basic Research Program of Shaanxi Province

Scientific Research Plan Projects of Shaanxi Education Department

National Key Research and Development Program of China

National Natural Science Foundation of China

China Postdoctoral Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

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