The theoretical chemical calculations clarify the mechanism of beta-alkylation of 1-phenylethanol with benzyl alcohol catalyzed by iron(ii) acetylacetonate methods-Reference-Cited by-同舟云学术

The theoretical chemical calculations clarify the mechanism of beta-alkylation of 1-phenylethanol with benzyl alcohol catalyzed by iron(ii) acetylacetonate methods

Published:2018 Issue:43 Volume:8 Page:24154-24165
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Feng Wei¹²³⁴⁵,Zhao Junfeng⁶⁷⁸⁹¹⁰,Wei Aiwen¹²³⁴⁵,Zhang Dandan¹²³⁴⁵,Liu Huiling¹²³⁴⁵^ORCID,Huang Xuri¹²³⁴⁵,Sun Kai¹¹³¹²¹⁰

Affiliation:

1. Laboratory of Theoretical and Computational Chemistry

2. Institute of Theoretical Chemistry

3. Jilin University

4. Technology Building of Jilin University

5. Changchun 130023

6. Department of Materials

7. School of Technology

8. Yantai Nanshan University

9. Longkou

10. China

11. School of Pharmaceutical Sciences

12. Changchun 130021

Abstract

Iron(ii) acetylacetonate was suggested to be a better catalyst of the β-alkylation of 1-phenylethanol with benzyl alcohol to form 1,3-diphenyl-1-propanol.

Funder

National Natural Science Foundation of China

Education Department of Jilin Province

Shandong University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/RA/C8RA03735C

Reference37 articles.

1. Hydroxy Chalcogenide-Promoted Morita-Baylis-Hillman Alkylation Reaction: Intermolecular Applications with Alkyl Halides as Electrophiles

2. Chemoselective Radical Dehalogenation and C–C Bond Formation on Aryl Halide Substrates Using Organic Photoredox Catalysts

3. Sulfamic acid as a cost-effective and recyclable solid acid catalyst for Friedel–Crafts alkylation of indole with α,β-unsaturated carbonyl compound and benzyl alcohol

4. Palladium-Catalyzed Oxidative Heck-Type Alkylation/Aryl Migration/Desulfonylation between Alkenes with α-Carbonyl Alkyl Bromides

5. Nickel-Catalyzed Direct Alkylation of Heterocycles with α-Bromo Carbonyl Compounds: C3-Selective Functionalization of 2-Pyridones

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