Facile preparation of organosilanes from benzylboronates and gem-diborylalkanes mediated by KOtBu-Reference-Cited by-同舟云学术

Facile preparation of organosilanes from benzylboronates and gem-diborylalkanes mediated by KO^tBu

Published:2023 Issue:26 Volume:14 Page:7355-7360
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Tang Man¹,Zhu Wenyan¹,Sun Huaxing¹,Wang Jing¹,Jing Su¹^ORCID,Wang Minyan²,Shi Zhuangzhi²^ORCID,Hu Jiefeng¹^ORCID

Affiliation:

1. School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing, 211816, China

2. State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, China

Abstract

A deboronative silylation of readily available benzylboronates and diborylalkanes with chlorosilanes has been developed using an alkoxide base. This approach enables the synthesis of benzyl silanes and silylboronates in practical and selective ways.

Funder

National Natural Science Foundation of China

Nanjing Tech University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC02461J

Reference60 articles.

1. Organosilicon Molecules with Medicinal Applications

2. Quest for Novel Chemical Entities through Incorporation of Silicon in Drug Scaffolds

3. The chemistry of organo silanetriols

4. Conjugated Polymers Inspired by Crystalline Silicon

5. Silyl-substituted 1,3-butadienes for Diels–Alder reaction, ene reaction and allylation reaction

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